Pembentukan atau Genesa Nikel Laterit
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. . . Nikel yang terbentuk dalam ledakan supernova?
Ini adalah Fakta Alam Nikel!
Miliaran tahun lalu, semua nikel yang saat ini di bumi tercipta dalam ledakan supernova. Ini adalah satu-satunya tempat di alam, di mana kondisi suhu dan tekanannya cukup untuk atom nikel terbentuk.
Bagaimana Nikel Diproduksi
Nikel laterite merupakan sumber bahan tambang yang sangat penting, menyumbang terhadap 40% dari produksi nikel dunia. Ditambang di lebih dari 23 negara dan dilebur atau dimurnikan di 25 negara. Endapan nikel laterite terbentuk dari hasil pelapukan dari dalam batuan induk dari jenis ultrabasa. Umumnya terbentuk pada iklim tropis sampai sub-tropis. Saat ini kebanyakan nikel laterite memang terbentuk di daerah ekuator.
Yang paling utama terdapat di Rusia, Kanada, Kaledonia Baru, Australia, Indonesia, Kuba, Cina, Afrika Selatan, Republik Dominika, Botswana, Columbia, Yunani dan Brazil. Kilang nikel penting lainnya juga beroperasi di Norwegia, Finlandia, Perancis, Jepang dan Inggris.
Nikel primer diproduksi dan digunakan dalam bentuk nikel ferro, nikel oksida, bahan kimia lainnya, dan sebagai tambahan atau logam nikel kurang murni. Nikel juga mudah didaur ulang dari banyak penerapannya, dan besar tonase dari sekunder atau "scrap" nikel digunakan untuk melengkapi logam yang baru ditambang.
Hanya sekitar 1,4 juta ton nikel baru atau primer diproduksi dan digunakan setiap tahun di dunia, dibandingkan dengan lebih dari 10 juta ton tembaga dan hampir 800 juta ton baja. Sumber: nickelinstitute.org
Bagaimana Pembentukan atau Genesa Nikel Laterit
Berbagai teori genesis bijih menjelaskan bagaimana, berbagai jenis deposit mineral terbentuk dalam kerak bumi. Teori genesis bijih tergantung pada mineral atau komoditi tersebut.
Teori genesis bijih umumnya melibatkan tiga komponen: source, transport atau konduit, dan trap. Hal ini juga berlaku untuk industri minyak bumi, yang pertamakali menggunakan metodologi ini.
Istilah “ laterite ” bisa diartikan sebagai endapan yang kaya akan iron-oxide, miskin unsure silica dan secara intensif ditemukan pada endapan lapukan pada iklim tropis (eggleton, 2001). Ada juga yang mengartikan nikel laterite sebagai endapan lapukan yang mengandung nikel dan secara ekonomis dapat di tambang.
Batuan induk dari endapan Nikel Laterite adalah batuan ultrabasa; umumnya harzburgite (peridotite yang kaya akan unsur ortopiroksen), dunite dan jenis peridotite yang lain.
Deposit nikel umumnya terbentuk pada batuan ultrabasa dengan kandungan Fe olivin yang tinggi dan Nikel berkadar antara 0.2% - 0.4% wt. Secara mineralogi nikel laterite dapat dibagi kedalam tiga kategori (Brand et al.,1998)
Hydrous Silicate Deposits
Profil dari type ini dari vertical dari bawah ke ata : Ore horizon pada lapisan saprolite (Mg-Ni silicate), grade Nikel antara 1.8% – 2.5%. Pada zona ini berkembang box-works, veining, relic structure, fracture, grain boundaries dan dapat berbentuk mineral; garnierite (max. 40% Ni). Ni terurai (Leached) dari fase limonite (Fe oxyhydroxide) dan disimpan dengan mineral silikat hidrat atau elemen pengganti Mg dalam serpentinit yang berubah (Pelletier, 1996).
Jadi, meskipun nikel laterit adalah hasil pelapukan, tetapi dapat dikatakan juga bahwa proses enrichment supergen sangat penting dalam pembentukan dan nilai ekonomi silikat hidrat dalam pengendapan ini. Jenis ini dapat ditemukan pada beberapa tempat seperti di Kaledonia Baru, Indonesia, Philippina,Dominika dan Columbia.
Clay Silicate Deposits
Pada jenis endapan ini, Si hanya sebagian terlarut oleh melalui groundwater. Si yang tersisa akan bergabung dengan Fe,Ni,dan Al untuk membentuk mineral lempung (clay minerals) seperti Ni-rich Notronite pada bagian tengah profil saprolite (see profile). Ni-rich serpentine juga dapat di replace oleh smectite atau kuarsa jika profile deposit ini tetap kontak dalam waktu lama dengan groundwater. Ni grade pada endapan ini lebih rendah dari Hydrosilicate deposit (1.2%;Brand et all,1998).
Oxide Deposits
Type terakhir adalah Oxide. Profile bawah menunjukkan Protolith dari jenis harzburgitic peridotites (mostly mineral olivine,serpentine, piroksen), sangat rentan terhadap pelapukan terutama di daerah tropis. Diatasnya terbentuk saprolite dan mendekati permukaan terbentuk limonite dan ferricrete (dipermukaan) ( see profile). Pada tipe deposit oxide ini, Nikel berasosiasi dengan Goethite (FeOOH) dan Mn Oxide.
Sebagai tambahan, Nikel laterite sangat jarang atau tidak sama sekali terbentuk pada batuan carbonate mengandung mineral talc.
Tectonics Setting
Nikel laterite berkembang di kompleks Ophiolite pada rentang waktu Phanerozoic, terutama Cretaseous-Miosen. Ophiolite ini telah mengalami fault dan joint sebagai efek dari tectonic uplift dapat memicu intensitas pelapukan dan perubahan pada water table level. Deposit Nikel lainnya ditemukan pada Archean Craton tergolong stabil berasosiasi dengan layer mafic complexes and komatiite (Butt,1975). Semakin banyak zona shear dan steep fault ( normal??), semakin tinggi pula tingkat enrichment proses untuk menghasilkan grade Nikel yang tinggi. Sebaliknya, zona thrust fault berasosiasi dengan emplacement kompleks ophiolite dan bersama dengan greenstone membentuk zona serpentine milonite atau talc-carbonates-altered ultramafic rocks. Komposisi seperti itu tidak memungkinkan terbentuknya Nikel pada endapan residu (regolith/lapukan).
Kondisi Topografi dan Morfologi
Dua faktor tersebut sangat penting dalam endapan nikel laterit karena kaitannya dengan posisi water table, stuktur dan drainage. Zona enrichment nikel laterite berada di topografi bagian atas (upper hill slope,crest, plateau, atau terrace). Kondisi water table pada zona ini dangkal,apalagi ditambah dengan adanya zona patahan n shear or joint. In consequence, akan mempercepat proses palarutan kimia (leaching processes) dan pada akhirnya akan terbentuk endapan saprolite mengandung nikel yang cukup tebal. Kondisi seperti ini dapat dijumpai di beberapa tempat sepeti Indonesia,New Caledonia, Ural (Russia) dan Columbia. Sebaliknya, pada topografi yang rendah, water table yang dalam akan menghambat proses pelarutan unsur – unsur dari batuan induk (baca:enrichment proses).
Faktor-faktor yang memengaruhi pembentukan bijih nikel laterit ini adalah:
a. Batuan asal. Adanya batuan asal merupakan syarat utama untuk terbentuknya endapan nikel laterit, macam batuan asalnya adalah batuan ultra basa. Dalam hal ini pada batuan ultra basa tersebut:
- terdapat elemen Ni yang paling banyak di antara batuan lainnya
- mempunyai mineral-mineral yang paling mudah lapuk atau tidak stabil, seperti olivin dan piroksin
- mempunyai komponen-komponen yang mudah larut dan memberikan lingkungan pengendapan yang baik untuk nikel.
b. Iklim. Adanya pergantian musim kemarau dan musim penghujan dimana terjadi kenaikan dan penurunan permukaan air tanah juga dapat menyebabkan terjadinya proses pemisahan dan akumulasi unsur-unsur. Perbedaan temperatur yang cukup besar akan membantu terjadinya pelapukan mekanis, dimana akan terjadi rekahan-rekahan dalam batuan yang akan mempermudah proses atau reaksi kimia pada batuan.
Tempat – tempat yang beriklim tropis seperti Indonesia dan Kolumbia memungkinkan untuk terjadinya proses pembentukan endapan Nikel laterite. Kondisi curah hujan yang tinggi, temperatur yang hangat, ditambah dengan aktivitas biogenic akan mempercepat proses pelapukan kimia, dimana Nikel laterite bisa mudah terbentuk.
c. Reagen-reagen kimia dan vegetasi. reagen-reagen kimia adalah unsur-unsur dan senyawa-senyawa yang membantu mempercepat proses pelapukan. Air tanah yang mengandung CO2 memegang peranan penting di dalam proses pelapukan kimia. Asam-asam humus menyebabkan dekomposisi batuan dan dapat mengubah pH larutan. Asam-asam humus ini erat kaitannya dengan vegetasi daerah.
Dalam hal ini, vegetasi akan mengakibatkan:
• penetrasi air dapat lebih dalam dan lebih mudah dengan mengikuti jalur akar pohon-pohonan.
• akumulasi air hujan akan lebih banyak.
• humus akan lebih tebal.
Keadaan ini merupakan suatu petunjuk, dimana hutannya lebat pada lingkungan yang baik akan terdapat endapan nikel lebih tebal dengan kadar lebih tinggi. Selain itu, vegetasi dapat berfungsi untuk menjaga hasil pelapukan terhadap erosi mekanis.
d. Struktur. Struktur yang sangat dominan lebih terdapat didaerah Polamaa ini adalah struktur kekar (joint) dibandingkan terhadap struktur patahannya. Seperti diketahui, batuan beku mempunyai porositas dan permeabilitas yang kecil sekali sehingga penetrasi air sangat sulit, maka dengan adanya rekahan-rekahan tersebut akan lebih memudahkan masuknya air dan berarti proses pelapukan akan lebih intensif.
e. Topografi. Keadaan topografi setempat akan sangat memengaruhi sirkulasi air beserta reagen-reagen lain. Untuk daerah landai, maka air akan bergerak perlahan-lahan sehingga akan mempunyai kesempatan untuk mengadakan penetrasi lebih dalam melalui rekahan-rekahan atau pori-pori batuan. Akumulasi andapan umumnya terdapat pada daerah-daerah landai sampai pada kemiringan sedang, hal ini menerangkan bahwa ketebalan pelapukan mengikuti bentuk topografi. Pada daerah curam, secara teoritis, jumlah air yang meluncur (run off) lebih banyak daripada air yang meresap ini dapat menyebabkan pelapukan kurang intensif.
f. Waktu. Waktu yang cukup lama akan mengakibatkan, pelapukan yang cukup intensif karena akumulasi unsur nikel cukup tinggi.
Profil nikel laterit keseluruhan terdiri dari 4 zona gradasi sebagai berikut :
1. Iron Capping. Merupakan bagian yang paling atas dari suatu penampang laterit. Komposisinya adalah akar tumbuhan, humus, oksida besi dan sisa-sisa organik lainnya. Warna khas adalah coklat tua kehitaman dan bersifat gembur. Kadar nikelnya sangat rendah sehingga tidak diambil dalam penambangan. Ketebalan lapisan tanah penutup rata-rata 0,3 s/d 6 m. berwarna merah tua, merupakan kumpulan massa goethite dan limonite. Iron capping mempunyai kadar besi yang tinggi tapi kadar nikel rendah. Terkadang terdapat mineral-mineral hematite, chromiferous.
2. Limonite Layer, Merupakan hasil pelapukan lanjut dari batuan beku ultrabasa. Komposisinya meliputi oksida besi lebih dominan, goethit, dan magnetit. Ketebalan lapisan ini rata-rata 8-15 m. Dalam limonit dapat dijumpai adanya akar tumbuhan, meskipun dalam persentasenya sangat kecil. Kemunculan bongkah-bongkah batuan beku ultrabasa pada zona ini tidak dominan atau hampir tidak ada, umumnya mineral-mineral di batuan beku basa-ultrabasa telah terubah menjadi serpentin akibat hasil dari pelapukan yang belum tuntas. fine grained, merah coklat atau kuning, lapisan kaya besi dari limonit soil menyelimuti seluruh area. Lapisan ini tipis pada daerah terjal, dan sempat hilang karena erosi. Sebagian dari nikel pada zona ini hadir di dalam mineral manganese oxide, lithiophorite. Terkadang terdapat mineral talc, tremolite, chromiferous, quartz, gibsite, maghemite.
3. Silika Boxwork, putih – orange chert, quartz, mengisi sepanjang fractured dan sebagian menggantikan zona terluar dari unserpentine fragmen peridotite, sebagian mengawetkan struktur dan tekstur dari batuan asal. Terkadang terdapat mineral opal, magnesite. Akumulasi dari garnierite-pimelite di dalam boxwork mungkin berasal dari nikel ore yang kaya silika. Zona boxwork jarang terdapat pada bedrock yang serpentinized.
4. Saprolite, Zona ini merupakan zona pengayaan unsur Ni. Komposisinya berupa oksida besi, serpentin sekitar < 0,4% kuarsa magnetit dan tekstur batuan asal yang masih terlihat. Ketebalan lapisan ini berkisar 5-18 m. Kemunculan bongkah-bongkah sangat sering dan pada rekahan-rekahan batuan asal dijumpai magnesit, serpentin, krisopras dan garnierit. Bongkah batuan asal yang muncul pada umumnya memiliki kadar SiO2 dan tinggi MgO serta Ni dan rendah Fe. campuran dari sisa-sisa batuan, butiran halus limonite, saprolitic rims, vein dari endapan garnierite, nickeliferous quartz, mangan dan pada beberapa kasus terdapat silika boxwork, bentukan dari suatu zona transisi dari limonite ke bedrock. Terkadang terdapat mineral quartz yang mengisi rekahan, mineral-mineral primer yang terlapukkan, chlorite. Garnierite di lapangan biasanya diidentifikasi sebagai kolloidal talc dengan lebih atau kurang nickeliferous serpentin. Struktur dan tekstur batuan asal masih terlihat.
5. Bedrock, bagian terbawah dari profil laterit. Tersusun atas bongkah yang lebih besar dari 75 cm dan blok peridotit (batuan dasar) dan secara umum sudah tidak mengandung mineral ekonomis (kadar logam sudah mendekati atau sama dengan batuan dasar). Batuan dasar merupakan batuan asal dari nikel laterit pada umumnya merupakan batuan beku ultrabasa yaitu harzburgit dan dunit pada rekahannya telah terisi oleh oksida besi 5-10%, garnierit minor dan silika > 35%. Permeabilitas batuan dasar meningkat sebanding dengan intensitas serpentinisasi.Zona ini terfrakturisasi kuat, kadang membuka, terisi oleh mineral garnierite dan silika. Frakturisasi ini diperkirakan menjadi penyebab adanya root zone yaitu zona high grade Ni, akan tetapi posisinya tersembunyi.
NIKEL
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• Tidak berkarat
• Tahan terhadap asam encer
Bijih nikel utam adalah nikel sulfida . Nikel-nikel yang diekspor dalam bentuk 3 macam yaitu bijih, nikel kasar, dan ferronikel. Daerah penambangan nikel ada di Koala, Soroako, Maluku Utara.
Cara penambangan nikel melalui berbagai cara , antara lain ;
• Penebangan pohon dan semak
• Pengupasan tanah permukaan
• Penggalian dengan sistem tangga (benching system) yaitu dimulai dari bawah ke atas mengikuti garis kontur dengan alat gali power shovel atau dozer shovel
Pengolahan nikel melalui beberapa tahap , yaitu :
• Pemanggangan
• Peleburan
• Elektrolisis
Penggunaan Nikel
• Untuk melapisi barang, terbuat dari; besi, tembaga, baja karena nikel mempunyai sifat keras, tahan korosi dan mudah mengkilap jika digosok.
• Untuk membuat baja tahan karat (stailess stell)
• Untuk membuat aliase dengan tembaga dan beberapa logam lain seperti :
a. Monel (Ni, Cu, Fe)
Digunakan untuk membuat instrumen tranmisi listrik
b. Nikrom(Ni,Fe,Cr)
Digunakan sebagai kawat pemanas
c. Alniko (Al, Ni, fe, Co)
Untuk membuat magnet.
d. Palinit dan Invar yaitu paduan nikel, mempunyai koefisien memuai sama halnya dengan gelas yang digunakan sebagai kawat listrik dan ditanam dalam kaca, misalnya pada bolam lampu pijar.
e. Serbuk nikel digunakan sebagai katalisator, misalnya pada hidrogenansi (pemadatan) minyak kelapa, juga pada cracking minyak bumi.